Issue 11, 2009
From the journal:

Green Chemistry

Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

Kazushi Arataa  

a Hokkaido University of Education, Department of Science, Hachiman-cho 1-2, Hakodate, Japan

Abstract

Recent studies on organic syntheses catalyzed by solid superacids, which are sulfate-supported metal oxides and tungsten- or molybdenum-supported metal oxides, are reviewed. The synthetic reactions are Friedel–Crafts acylations, reactions between amines and ketones, esterifications of acids with alcohols, and others. The catalysts are satisfactorily active in a heterogeneous liquid–solid system, recoverable, and reusable, and they offer new opportunities for developing environmentally benign and friendly processes in organic syntheses.

Graphical abstract: Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

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Article information

DOI
https://doi.org/10.1039/B822795K
Article type
Tutorial Review
Submitted
18 Dec 2008
Accepted
12 Aug 2009
First published
17 Sep 2009

Green Chem., 2009,11, 1719-1728

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Organic syntheses catalyzed by superacidic metal oxides: sulfated zirconia and related compounds

K. Arata, Green Chem., 2009, 11, 1719 DOI: 10.1039/B822795K

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