A 3 × 3 matrix of manisyl (4-methoxy-2,6-dimethylphenyl) substituted pyridyl-1,10-phenanthrolines has been synthesized by utilizing a general palladium catalyzed cross-coupling procedure. The directionality of these terdentate ligands will generate chiral octahedral ML2 complexes, potentially useful for the metal templated synthesis of topologically chiral structures.
J. K. Klosterman, A. Linden and J. S. Siegel, Org. Biomol. Chem., 2008, 6, 2755 DOI: 10.1039/B804106G
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