Issue 24, 2008

Mechanistic investigation of the gold-catalyzed aerobic oxidation of aldehydes: added insight from Hammett studies and isotopic labelling experiments

Abstract

The gold-catalyzed aerobic oxidation of aldehydes proceeds through development of a partial negative charge and has a significant kinetic isotope effect (kH/kD = 2.8–2.9), which illustrates that activation of the C–H bond takes place in the rate-determining step.

Graphical abstract: Mechanistic investigation of the gold-catalyzed aerobic oxidation of aldehydes: added insight from Hammett studies and isotopic labelling experiments

Supplementary files

Article information

Article type
Communication
Submitted
26 Feb 2008
Accepted
05 Mar 2008
First published
31 Mar 2008

Chem. Commun., 2008, 2750-2752

Mechanistic investigation of the gold-catalyzed aerobic oxidation of aldehydes: added insight from Hammett studies and isotopic labelling experiments

P. Fristrup, L. Bahn Johansen and C. Hviid Christensen, Chem. Commun., 2008, 2750 DOI: 10.1039/B803270J

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