Issue 30, 2008

Reductive elimination of C6F5–C6F5 in the reaction of bis(pentafluorophenyl)palladium(ii) complexes with protic acids

Abstract

Reductive elimination of C6F5–C6F5 from cis-[Pd(C6F5)2L] (L = cod, bpy, and dppb) was promoted by Brønsted acids. HNO3 is a convenient acid for the formation of C6F5–C6F5 from [Pd(C6F5)2(cod)]. The products are controlled by the auxiliary ligand.

Graphical abstract: Reductive elimination of C6F5–C6F5 in the reaction of bis(pentafluorophenyl)palladium(ii) complexes with protic acids

Supplementary files

Article information

Article type
Communication
Submitted
12 Feb 2008
Accepted
09 May 2008
First published
03 Jun 2008

Dalton Trans., 2008, 3949-3952

Reductive elimination of C6F5–C6F5 in the reaction of bis(pentafluorophenyl)palladium(II) complexes with protic acids

T. Koizumi, A. Yamazaki and T. Yamamoto, Dalton Trans., 2008, 3949 DOI: 10.1039/B802408A

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