Issue 20, 2008
From the journal:

Chemical Communications

Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds†

Mateo Alajarín,*a   José Berná,*a   Carmen López-Leonardoa  and  Jonathan W. Steedb  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, Spain
E-mail: alajarin@um.es, ppberna@um.es
Fax: +34 968 364149
Tel: +34 968 367497

b Department of Chemistry, University of Durham, South Road, Durham, UK

Abstract

Macrobicyclic triphosphazides are able to reversibly exchange one of their tripodal components by means of a dynamic disassembly–reassembly process; surprisingly this strategy provides better yields of cage compounds than a direct tripod–tripod coupling.

Graphical abstract: Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds

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Article information

DOI
https://doi.org/10.1039/B801299G
Article type
Communication
Submitted
23 Jan 2008
Accepted
27 Feb 2008
First published
14 Mar 2008

Chem. Commun., 2008, 2337-2339

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Component exchange as a synthetically advantageous strategy for the preparation of bicyclic cage compounds

M. Alajarín, J. Berná, C. López-Leonardo and J. W. Steed, Chem. Commun., 2008, 2337 DOI: 10.1039/B801299G

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