Issue 19, 2008
From the journal:

Chemical Communications

A “jellyfish” shaped green emitting gallium(iii)-containing metallomesogen†‡

Daniela Pucci,*a   Iolinda Aiello,a   Anna Bellusci,a   Alessandra Crispini,a   Irene De Franco,a   Mauro Ghedinia  and  Massimo La Dedaa  

* Corresponding authors

a Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM Unità INSTM della Calabria and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, Arcavacata di Rende (CS), Italy
E-mail: d.pucci@unical.it
Fax: 39 0984 492066
Tel: 39 0984 492064

Abstract

The synthesis of the first gallium(III)-based liquid crystal has been achieved grafting around the metal centre two chelating 2-methylquinolin-8-olate anions and one monodentate 3,4,5-tris(hexadecyloxy)benzoyloxy ligand, allowing the resulting complex to be a soft luminescent material with the typical high quantum yield of pentacordinated gallium species.

Graphical abstract: A “jellyfish” shaped green emitting gallium(iii)-containing metallomesogen

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Article information

DOI
https://doi.org/10.1039/B800030A
Article type
Communication
Submitted
03 Jan 2008
Accepted
19 Feb 2008
First published
13 Mar 2008

Chem. Commun., 2008, 2254-2256

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A “jellyfish” shaped green emitting gallium(III)-containing metallomesogen

D. Pucci, I. Aiello, A. Bellusci, A. Crispini, I. De Franco, M. Ghedini and M. La Deda, Chem. Commun., 2008, 2254 DOI: 10.1039/B800030A

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