Issue 5, 2008
From the journal:

CrystEngComm

A chiral C3-symmetric hexanuclear triangular-prismatic copper(ii) cluster derived from a highly modular dipeptidic N,N′-terephthaloyl-bis(S-aminocarboxylato) ligand†‡

Barbara Wisser,a   Anne-Christine Chamayou,a   Robert Miller,b   Wolfgang Schererb  and  Christoph Janiak*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 21, Freiburg, Germany
E-mail: janiak@uni-freiburg.de
Fax: +49 761 2036147
Tel: +49 761 2036127

b Lehrstuhl für Chemische Physik und Materialwissenschaften, Universität Augsburg, Universitätsstr. 1, D-86159, Augsburg, Germany
E-mail: wolfgang.scherer@physik.uni-augsburg.de
Fax: +49 821 5983227
Tel: +49 821 5983351

Abstract

The enantiomeric dipeptidic ligand N,N′-terephthaloyl-bis(L-phenylalaninato) (TBPhe2–) reacts with copper(II) acetate in ethanol under the formation of the hexanuclear double-layered triangular-prismatic cluster [Cu2(μ4-TBPhe-κO : κO′ : κO″ : κO′″)2(EtOH)(H2O)]3·∼28(H2O/0.33EtOH) with C3-symmetry, homochiral conformer assembly in the crystal and strong antiferromagnetic coupling within the Cu2(O2CR)4 paddle-wheel unit (J = −214 K).

Graphical abstract: A chiral C3-symmetric hexanuclear triangular-prismatic copper(ii) cluster derived from a highly modular dipeptidic N,N′-terephthaloyl-bis(S-aminocarboxylato) ligand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B717207A
Article type
Communication
Submitted
07 Nov 2007
Accepted
03 Jan 2008
First published
23 Jan 2008

CrystEngComm, 2008,10, 461-464

Permissions

Request permissions

A chiral C3-symmetric hexanuclear triangular-prismatic copper(II) cluster derived from a highly modular dipeptidic N,N′-terephthaloyl-bis(S-aminocarboxylato) ligand

B. Wisser, A. Chamayou, R. Miller, W. Scherer and C. Janiak, CrystEngComm, 2008, 10, 461 DOI: 10.1039/B717207A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements