Issue 43, 2007
From the journal:

Chemical Communications

Reactive MALDI mass spectrometry: application to high mass alkanes and polyethylene†

William E. Wallacea  

a Polymers Division, National Institute of Standards and Technology, 100 Bureau Drive, Stop 8541, Gaithersburg, USA
E-mail: William.Wallace@nist.gov
Fax: (+1 301) 975-3928
Tel: (+1 301) 975-5886

Abstract

A molecular solid of fullerene (C60) intercalated with cobalt cyclopentadienyl dicarbonyl (CoCp(CO)2) was shown to be an effective matrix for matrix-assisted laser desorption/ionization mass spectrometry (MALDI) of large alkanes (demonstrated up to C94H190) and polyethylenes that otherwise cannot be produced as intact ions in the gas phase.

Graphical abstract: Reactive MALDI mass spectrometry: application to high mass alkanes and polyethylene

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Article information

DOI
https://doi.org/10.1039/B711932A
Article type
Communication
Submitted
03 Aug 2007
Accepted
15 Aug 2007
First published
21 Aug 2007

Chem. Commun., 2007, 4525-4527

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Reactive MALDI mass spectrometry: application to high mass alkanes and polyethylene

W. E. Wallace, Chem. Commun., 2007, 4525 DOI: 10.1039/B711932A

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