Issue 45, 2007
From the journal:

Chemical Communications

NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(μ-CO)4(μ-OOCCMe3)8[μ-N([double bond, length as m-dash]O)O–]4†

Tatiana A. Stromnova,*a   Oleg N. Shishilov,a   Andrei V. Churakov,a   Lyudmila G. Kuz'minaa  and  Judith A. K. Howardb  

* Corresponding authors

a N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninsky pr., 31, Moscow, Russian Federation
E-mail: strom@igic.ras.ru
Fax: 74959541279
Tel: 74959554805

b Department of Chemistry, University of Durham, South Road, Durham, UK

Abstract

Interaction of Pd-clusters [Pd(CO)(OCOR)]n with NO was investigated, these Pd-clusters were found to promote the NO disproportionation into N2 and NO2− in mild conditions; an eight-nuclear palladium cluster Pd8(μ-CO)4(μ-OOCCMe3)8(μ-NO2)4 with a new type of structure and an uncommon set of ligands was characterized by X-ray diffraction analysis.

Graphical abstract: NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(μ-CO)4(μ-OOCCMe3)8[μ-N( [[double bond, length as m-dash]] O)O–]4

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B710230E
Article type
Communication
Submitted
10 Jul 2007
Accepted
29 Aug 2007
First published
10 Sep 2007

Chem. Commun., 2007, 4800-4802

Permissions

Request permissions

NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(μ-CO)4(μ-OOCCMe3)8[μ-N([double bond, length as m-dash]O)O–]4

T. A. Stromnova, O. N. Shishilov, A. V. Churakov, L. G. Kuz'mina and J. A. K. Howard, Chem. Commun., 2007, 4800 DOI: 10.1039/B710230E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements