Issue 41, 2007

General formation of trigonal-prismatic [Ag6X5(dppf)3]+ (X = Cl, Br, I) through an unusual ligand migration from NiX2(dppf) to AgOTf

Abstract

Use of NiX2(dppf) (X = Cl, Br, I) as a ligand transfer reagent to AgOTf results in the trigonal prismatic [Ag6X5(dppf)3]OTf complexes. Similar reactions with the dppe analogues give at least 4 different types of dppe-bridged coordination polymers.

Graphical abstract: General formation of trigonal-prismatic [Ag6X5(dppf)3]+ (X = Cl, Br, I) through an unusual ligand migration from NiX2(dppf) to AgOTf

Supplementary files

Article information

Article type
Communication
Submitted
14 May 2007
Accepted
01 Jun 2007
First published
20 Jun 2007

Chem. Commun., 2007, 4221-4223

General formation of trigonal-prismatic [Ag6X5(dppf)3]+ (X = Cl, Br, I) through an unusual ligand migration from NiX2(dppf) to AgOTf

P. Teo, L. L. Koh and T. S. A. Hor, Chem. Commun., 2007, 4221 DOI: 10.1039/B707218J

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