Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters

Antonello Filippi; Anna Giardini; Enrico Marcantoni; Alessandra Paladini; Susanna Piccirillo; Gabriele Renzi; Flaminia Rondino; Graziella Roselli; Mauro Satta; Maurizio Speranza

doi:10.1039/B702257N

Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters†‡

Antonello Filippi,^a Anna Giardini,^b Enrico Marcantoni,^c Alessandra Paladini,^b Susanna Piccirillo,^d Gabriele Renzi,^c Flaminia Rondino,^a Graziella Roselli,^c Mauro Satta^e and Maurizio Speranza*^a

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^a Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università “La Sapienza”, Roma, Italy
E-mail: maurizio.speranza@uniroma1.it
Fax: +39 06 49913602

^b Dipartimento di Chimica, Università “La Sapienza”, Roma, Italy, and CNR-IMIP (Pz), Italy

^c Dipartimento di Scienze Chimiche, Università degli Studi di Camerino, Camerino (Mc), Italy

^d Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, Roma, Italy

^e CNR- ISC (Istituto dei Sistemi Complessi), Roma, Italy

Abstract

The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the π-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite π-faces of the chiral arene itself.

Physical Chemistry Chemical Physics

Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters†‡

Abstract

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Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters

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