Issue 29, 2006
From the journal:

Chemical Communications

Highly diastereoselective formation and reactions of a non-mesomerically stabilized, lithiated α-thiocarbanion†

Ravindra P. Sonawane,a   Roland Fröhlich‡a  and  Dieter Hoppe*a  

* Corresponding authors

a Organisch-Chemisches Institut der Universität, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, Münster, Germany
E-mail: dhoppe@uni-muenster.de

Abstract

A new class of non-mesomerically stabilized, unbranched, configurationally stable lithiated α-thiocarbanion has been synthesized and its stereospecific reactions with several electrophiles were investigated.

Graphical abstract: Highly diastereoselective formation and reactions of a non-mesomerically stabilized, lithiated α-thiocarbanion

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Article information

DOI
https://doi.org/10.1039/B604029B
Article type
Communication
Submitted
20 Mar 2006
Accepted
23 May 2006
First published
14 Jun 2006

Chem. Commun., 2006, 3101-3103

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Highly diastereoselective formation and reactions of a non-mesomerically stabilized, lithiated α-thiocarbanion

R. P. Sonawane, R. Fröhlich and D. Hoppe, Chem. Commun., 2006, 3101 DOI: 10.1039/B604029B

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