Coordination of a monomeric diphosphido platinum complex as a bridging ligand†
Abstract
The reactions of cis-[Pt(C6F5)2(PPh2)2]2− with [AuClPPh3] or [Ag(OClO3)PPh3] yield the neutral heterotrinuclear complexes [M2Pt(μ-PPh2)2(C6F5)2(PPh3)2] (M = Au, Ag). Their structures have been established by