Issue 5, 2006

Constructing 2D porous material based on the assembly of large organic ions: p-sulfonatocalix[8]arene and tetraphenylphosphonium ions

Abstract

In the presence of tetraphenylphosphonium and aquated ytterbium(III) ions, conformationally flexible p-sulfonato-calix[8]arene forms an extended structure with two dimensional porosity involving the assembly of phosphonium cations and ‘molecular capsules’ comprised of two calixarenes shrouding three phosphonium cations.

Graphical abstract: Constructing 2D porous material based on the assembly of large organic ions: p-sulfonatocalix[8]arene and tetraphenylphosphonium ions

Supplementary files

Article information

Article type
Communication
Submitted
19 Oct 2005
Accepted
17 Nov 2005
First published
19 Dec 2005

Chem. Commun., 2006, 511-513

Constructing 2D porous material based on the assembly of large organic ions: p-sulfonatocalix[8]arene and tetraphenylphosphonium ions

M. Makha, A. N. Sobolev and C. L. Raston, Chem. Commun., 2006, 511 DOI: 10.1039/B514833B

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