Issue 2, 2006
From the journal:

Dalton Transactions

An unprecedented, reversible coordination mode rearrangement: η3(B–H) vs. η1(Sn) stanna-closo-dodecaborate coordination

Torben Gädta  and  Lars Wesemann*a  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, Tübingen, Germany
E-mail: lars.wesemann@uni.tuebingen.de
Fax: (49 7071 295306

Abstract

The synthesis of the ruthenium stanna-closo-dodecaborate complex [Bu3MeN]2[Ru(dppb)(MeCN)2(SnB11H11)2] by an unprecedented, reversible η3(B-H) to η1(Sn) rearrangement of [Bu3MeN]2[Ru(dppb)(SnB11H11)2] is described and the product is characterized by multinuclear NMR spectroscopy and single-crystal X-ray diffraction.

Graphical abstract: An unprecedented, reversible coordination mode rearrangement: η3(B–H) vs. η1(Sn) stanna-closo-dodecaborate coordination

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Article information

DOI
https://doi.org/10.1039/B514203M
Article type
Communication
Submitted
06 Oct 2005
Accepted
07 Oct 2005
First published
01 Nov 2005

Dalton Trans., 2006, 328-329

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An unprecedented, reversible coordination mode rearrangement: η3(B–H) vs. η1(Sn) stanna-closo-dodecaborate coordination

T. Gädt and L. Wesemann, Dalton Trans., 2006, 328 DOI: 10.1039/B514203M

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