Issue 86, 2005
From the journal:

CrystEngComm

Engineering organic/inorganic diols that reversibly capture and release volatile guests†

Alessia Bacchi,*a   Elsa Bosettia  and  Mauro Carcellia  

* Corresponding authors

a Dipartimento di Chimica Generale ed Inorganica, Chimica Analitica, Chimica Fisica, Università di Parma, Parco Area delle Scienze 17A, Parma, Italy
E-mail: alessia.bacchi@unipr.it

Abstract

The structural and clathrating behaviour of some trans-M(LOH)2Xn (M = Ag+, Pd2+; X = anion) complexes is studied. The role of anions and included solvent molecules in inducing supramolecular isomerism is discussed. The toolbox of supramolecular interactions which can be used for the assembly of these systems involves mainly OH⋯OH and OH⋯X hydrogen bonds, and can be mediated by the guest molecules (G) via OH⋯G interactions. The diverse supramolecular configurations of some anion-mediated Ag(LOH)2X (X = BF4, PF6) networks are analysed. In the solvent-mediated crystal networks of Pd(LOH)2X2·nG (X = Cl, I, CH3, CH3COO; G = acetone, tetrahydrofuran, dimethylsulfoxide, dimethylformamide, 1,4-dioxane), the substructures built by the solvent domains are discussed in relation to the solvation/desolvation processes.

Graphical abstract: Engineering organic/inorganic diols that reversibly capture and release volatile guests

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Article information

DOI
https://doi.org/10.1039/B507966G
Article type
Highlight
Submitted
06 Jun 2005
Accepted
15 Jul 2005
First published
03 Aug 2005

CrystEngComm, 2005,7, 527-537

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Engineering organic/inorganic diols that reversibly capture and release volatile guests

A. Bacchi, E. Bosetti and M. Carcelli, CrystEngComm, 2005, 7, 527 DOI: 10.1039/B507966G

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