Issue 29, 2005
From the journal:

Chemical Communications

A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology†

Chuan-De Wua  and  Wenbin Lin*a  

* Corresponding authors

a Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, USA
E-mail: wlin@unc.edu

Abstract

A novel homochiral 3D metal–organic framework [CdL2(H2O)2][ClO4]2·2DMF·3EtOH·5/3H2O, 1, (L = (R)-6,6′-dichloro-2,2′-diethoxy-1,1′-binaphthyl-4,4′-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.

Graphical abstract: A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

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Article information

DOI
https://doi.org/10.1039/B505916J
Article type
Communication
Submitted
26 Apr 2005
Accepted
25 May 2005
First published
15 Jun 2005

Chem. Commun., 2005, 3673-3675

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A chiral porous 3D metal–organic framework with an unprecedented 4-connected network topology

C. Wu and W. Lin, Chem. Commun., 2005, 3673 DOI: 10.1039/B505916J

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