Issue 26, 2005
From the journal:

Chemical Communications

A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides†

Kohsuke Mori,a   Yohei Mitani,a   Takayoshi Hara,a   Tomoo Mizugaki,a   Kohki Ebitania  and  Kiyotomi Kaneda*a  

* Corresponding authors

a Department of Materials Engineering Science, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan
E-mail: kaneda@cheng.es.osaka-u.ac.jp
Fax: +81-6-6850-6260
Tel: +81-6-6850-6260

Abstract

A zinc-based hydroxyapatite catalyst in conjunction with a Lewis base proved to be efficient for the coupling of CO2 and epoxide in the absence of additional organic solvents under an atmospheric CO2 pressure; the work-up procedure is straightforward and the catalyst could be reused without loss of catalytic activity and selectivity.

Graphical abstract: A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides

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Article information

DOI
https://doi.org/10.1039/B502636A
Article type
Communication
Submitted
24 Feb 2005
Accepted
28 Apr 2005
First published
27 May 2005

Chem. Commun., 2005, 3331-3333

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A single-site hydroxyapatite-bound zinc catalyst for highly efficient chemical fixation of carbon dioxide with epoxides

K. Mori, Y. Mitani, T. Hara, T. Mizugaki, K. Ebitani and K. Kaneda, Chem. Commun., 2005, 3331 DOI: 10.1039/B502636A

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