Issue 12, 2005
From the journal:

Chemical Communications

Spontaneous resolution in a halogen bonded supramolecular architecture†

Hannes Neukirch,a   Emanuela Guido,a   Rosalba Liantonio,a   Pierangelo Metrangolo,*a   Tullio Pilatib  and  Giuseppe Resnati*a  

* Corresponding authors

a NFMLab-Department of Chemistry, Materials and Chemical Engineering “G. Natta”, Polytechnic of Milan, Via L. Mancinelli 7, Milan, Italy
E-mail: giuseppe.resnati@polimi.it, pierangelo.metrangolo@polimi.it
Web: http://nfmlab.chem.polimi.it
Fax: +39 02 2399 3080
Tel: +39 02 2399 3032 (G. R.), 3041 (P. M.)

b C.N.R.-Institute of Molecular Sciences and Technologies, University of Milan, Via C. Golgi 19, Milan, Italy

Abstract

The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N′,N′-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.

Graphical abstract: Spontaneous resolution in a halogen bonded supramolecular architecture

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Article information

DOI
https://doi.org/10.1039/B417771A
Article type
Communication
Submitted
25 Nov 2004
Accepted
07 Jan 2005
First published
27 Jan 2005

Chem. Commun., 2005, 1534-1536

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Spontaneous resolution in a halogen bonded supramolecular architecture

H. Neukirch, E. Guido, R. Liantonio, P. Metrangolo, T. Pilati and G. Resnati, Chem. Commun., 2005, 1534 DOI: 10.1039/B417771A

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