Issue 8, 2005
From the journal:

Chemical Communications

Formation of novel anionic gold–tin cluster compounds

Siegbert Hagen,a   Lars Wesemann*a  and  Ingo Pantenburgb  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Tübingen, Auf der Morgenstelle 18, Tübingen, Germany
E-mail: lars.wesemann@uni-tuebingen.de
Fax: +49 7071 295306

b Institut für Anorganische Chemie der Universität zu Köln, Greinstrasse 6, Köln, Germany

Abstract

A straightforward procedure for the formation of mixed metal Au/Sn clusters is presented: reaction of the heteroborate [SnB11H11]2− with phosphine gold electrophiles gave the clusters [Bu3NH]3[{(Et3P)Au(SnB11H11)}3] and [Bu3MeN]4[{(dppm)Au2(SnB11H11)2}2], which were characterised by X-ray diffraction.

Graphical abstract: Formation of novel anionic gold–tin cluster compounds

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Article information

DOI
https://doi.org/10.1039/B416472E
Article type
Communication
Submitted
28 Oct 2004
Accepted
19 Nov 2004
First published
04 Jan 2005

Chem. Commun., 2005, 1013-1015

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Formation of novel anionic gold–tin cluster compounds

S. Hagen, L. Wesemann and I. Pantenburg, Chem. Commun., 2005, 1013 DOI: 10.1039/B416472E

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