Issue 5, 2005
From the journal:

Chemical Communications

New catalytic route to functionalized vinylboronates†

Bogdan Marciniec,*a   Magdalena Jankowskaa  and  Cezary Pietraszuka  

* Corresponding authors

a Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, Poznań, Poland
E-mail: marcinb@amu.edu.pl
Fax: (+48) 61 8291 508
Tel: (+48) 61 8291 509

Abstract

Vinylsubstituted boronates i.e. vinyldioxaborolane and vinyldioxaborinane react regioselectively with olefins in the presence of RuHCl(CO)(PCy3)2 with the formation of functionalized vinylboron derivatives. The reaction opens a new catalytic route for preparation of organoboranes.

Graphical abstract: New catalytic route to functionalized vinylboronates

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Article information

DOI
https://doi.org/10.1039/B414644A
Article type
Communication
Submitted
23 Sep 2004
Accepted
02 Nov 2004
First published
14 Dec 2004

Chem. Commun., 2005, 663-665

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New catalytic route to functionalized vinylboronates

B. Marciniec, M. Jankowska and C. Pietraszuk, Chem. Commun., 2005, 663 DOI: 10.1039/B414644A

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