Issue 16, 2004
From the journal:

Chemical Communications

Highly diastereoselective Prins-type cyclisation of cyclopropylvinylic aldehydes mediated by TiCl4†

Chan-Mo Yu,*a   Seok-Keun Yoon,a   Young-Taek Honga  and  Jimin Kima  

* Corresponding authors

a Department of Chemistry and Lab for Metal-Catalysed Reactions, Sungkyunkwan University, Suwon 440-746, Korea
E-mail: cmyu@chem.skku.ac.kr
Fax: +82 31 290 7075
Tel: +82 31 290 7067

Abstract

A novel intramolecular Prins type cyclisation of cyclopropylvinylic aldehydes 1 promoted by TiCl4 under mild reaction conditions to form cis-cyclic products 2 in high yields has been accomplished.

Graphical abstract: Highly diastereoselective Prins-type cyclisation of cyclopropylvinylic aldehydes mediated by TiCl4

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Article information

DOI
https://doi.org/10.1039/B406362G
Article type
Communication
Submitted
29 Apr 2004
Accepted
23 Jun 2004
First published
23 Jul 2004

Chem. Commun., 2004, 1840-1841

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Highly diastereoselective Prins-type cyclisation of cyclopropylvinylic aldehydes mediated by TiCl4

C. Yu, S. Yoon, Y. Hong and J. Kim, Chem. Commun., 2004, 1840 DOI: 10.1039/B406362G

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