Issue 14, 2004

Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(i) nitrene transfer catalysts

Abstract

New 1,10-phenanthroline ligands have been synthesized with C6F5– or 2,4,6-(CF3)3C6H2– groups in the 2- and 9-positions; a cationic copper(I) complex of the latter catalyses nitrene transfer to the C–H bonds of electron-rich arenes.

Graphical abstract: Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(i) nitrene transfer catalysts

Article information

Article type
Communication
Submitted
25 Mar 2004
Accepted
12 May 2004
First published
07 Jun 2004

Chem. Commun., 2004, 1628-1629

Oxidation-resistant, sterically demanding phenanthrolines as supporting ligands for copper(I) nitrene transfer catalysts

C. W. Hamilton, D. S. Laitar and J. P. Sadighi, Chem. Commun., 2004, 1628 DOI: 10.1039/B404515G

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