Structure and magnetism of a new pyrazolate bridged iron(II) spin crossover complex displaying a single HS–HS to LS–LS transition
Abstract
The dinuclear iron(II) complex [(pypzH)(NCSe)Fe(μ-pypz)2Fe(NCSe)(pypzH)].2H2O displays a single, sharp spin crossover transition between the [HS-HS] and [LS-LS] states and is structurally characterised above and below the T1/2 = 225 K value