Issue 24, 2003
From the journal:

Chemical Communications

Exo-metal coordination by a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 dimer in [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 {2-NC5H4 = 2-pyridyl, C5H5N = pyridine)†

Andrew D. Bond,a   Emma L. Doyle,a   Felipe García,a   Richard A. Kowenicki,a   Mary McPartlin,b   Lucía Rieraa  and  Dominic S. Wright*a  

* Corresponding authors

a Chemistry Department, Cambridge University, Lensfield Road, Cambridge, U.K.
E-mail: dsw1000@cus.cam.ac.uk.
Fax: 0044 (0)1223 36362
Tel: 0044 (0)1223 763122

b School of Chemistry, University of North London, London, U.K.

Abstract

The in situ reaction of the phosphazane dimer [ClP(µ-N-2-NC5H4)]2 (2) with CuCl in the presence of C5H5N/H2O gives the title complex [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 (1), containing a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 ligand which is isoelectronic with species of the type [{P(µ-NR)}2NR]2.

Graphical abstract: Exo-metal coordination by a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 dimer in [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 {2-NC5H4 = 2-pyridyl, C5H5N = pyridine)

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B309842G
Article type
Communication
Submitted
15 Aug 2003
Accepted
10 Oct 2003
First published
03 Nov 2003

Chem. Commun., 2003, 2990-2991

Permissions

Request permissions

Exo-metal coordination by a tricyclic [{P(µ-N-2-NC5H4)}2(µ-O)]2 dimer in [{P(µ-N-2-NC5H4)}2(µ-O)]2{CuCl·(C5H5N)2}4 {2-NC5H4 = 2-pyridyl, C5H5N = pyridine)

A. D. Bond, E. L. Doyle, F. García, R. A. Kowenicki, M. McPartlin, L. Riera and D. S. Wright, Chem. Commun., 2003, 2990 DOI: 10.1039/B309842G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements