Issue 22, 2003
From the journal:

Chemical Communications

Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N′-dioxide with metal(ii) thiocyanates: isostructurality in coordination networks bearing different mono- and di-nuclear nodes†‡

Lin-Ping Zhang,a   Wen-Jie Luab  and  Thomas C. W. Mak*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, New Territories, Hong Kong SAR, P. R. China
E-mail: tcwmak@cuhk.edu.hk
Fax: +852-2603-5057
Tel: +852-2609-6279

b Department of Chemical and Environmental Engineering, Wuyi University, Jiangmen, Guangdong Province, P. R. China

Abstract

The new flexible spacer ligand 1,3-bis(4-pyridyl)propane-N,N′-dioxide forms three classes of isomorphous compounds with metal(II) thiocyanates at controlled ligand–metal molar ratios, and its μ3-O,O,O′ mode leads to a pair of coordination networks having the same (4, 4) topological characteristics but different mono- and di-nuclear nodes.

Graphical abstract: Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N′-dioxide with metal(ii) thiocyanates: isostructurality in coordination networks bearing different mono- and di-nuclear nodes

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Article information

DOI
https://doi.org/10.1039/B307604K
Article type
Communication
Submitted
03 Jul 2003
Accepted
19 Sep 2003
First published
17 Oct 2003

Chem. Commun., 2003, 2830-2831

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Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N′-dioxide with metal(II) thiocyanates: isostructurality in coordination networks bearing different mono- and di-nuclear nodes

L. Zhang, W. Lu and T. C. W. Mak, Chem. Commun., 2003, 2830 DOI: 10.1039/B307604K

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