Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged PdI–PdI bond

S. Jo Ling Foo; Nathan D. Jones; Brian O. Patrick; Brian R. James

doi:10.1039/B300177F

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Diastereoselective formation of a dipalladium(i) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged Pd^I–Pd^I bond†

S. Jo Ling Foo,^a Nathan D. Jones,^a Brian O. Patrick^a and Brian R. James*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, University of British Columbia, Vancouver, B.C., Canada
E-mail: brj@chem.ubc.ca
Fax: +1-604-822-2847
Tel: +1-604-822-6645

Abstract

The ligand CH₂(P(o-C₆H₄NMe₂)₂)₂ (dmapm) gives access to the first example of a dipalladium(I) complex supported by a tetradentate ligand, Pd₂Cl₂(μ-N,P,P,N-dmapm), which, unlike the well-known Pd₂X₂(μ-dppm)₂ complexes (X = halide, dppm = bis(diphenylphosphino)methane), reacts with thiols to give addition of RS–H across a phosphine-bridged Pd–Pd bond.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B300177F
Article type: Communication
Submitted: 07 Jan 2003
Accepted: 06 Mar 2003
First published: 20 Mar 2003

Download Citation

Chem. Commun., 2003, 988-989

Permissions

Request permissions

Diastereoselective formation of a dipalladium(I) complex supported by a bridging tetradentate ligand, and oxidative addition of RS–H across a phosphine-bridged Pd^I–Pd^I bond

S. Jo Ling Foo, N. D. Jones, B. O. Patrick and B. R. James, Chem. Commun., 2003, 988 DOI: 10.1039/B300177F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications