Issue 14, 2003
From the journal:

CrystEngComm

Polarity formation in solid solutions: (4,4′-dinitrostilbene)1 − x(4-chloro-4′-nitrostilbene)x, 1 > x > 0

S. Kluge,a   I. Dohnke,a   F. Buddea  and  J. Hulliger*a  

* Corresponding authors

a University of Berne, Department of Chemistry and Biochemistry, Freiestrasse 3, Berne, Switzerland
E-mail: juerg.hulliger@iac.unibe.ch

Abstract

Solid solution formation is a safe way to polarity formation in organic crystals. Molecular recognition at surfaces brings in orientational disorder, which can lead to grow-in polarity. Basic features of as-grown solid solutions are revealed by a new technique called phase sensitive second harmonic microscopy. Crystals are twinned and grow into a bi-polar structure.

Graphical abstract: Polarity formation in solid solutions: (4,4′-dinitrostilbene)1 − x(4-chloro-4′-nitrostilbene)x, 1 > x > 0

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Article information

DOI
https://doi.org/10.1039/B211829G
Article type
Paper
Submitted
29 Nov 2002
Accepted
27 Jan 2003
First published
18 Feb 2003

CrystEngComm, 2003,5, 67-69

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Polarity formation in solid solutions: (4,4′-dinitrostilbene)1 − x(4-chloro-4′-nitrostilbene)x, 1 > x > 0

S. Kluge, I. Dohnke, F. Budde and J. Hulliger, CrystEngComm, 2003, 5, 67 DOI: 10.1039/B211829G

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