Issue 23, 2002
From the journal:

Chemical Communications

Heterometallic CeIII–FeIII–salicylate networks: models for corrosion mitigation of steel surfaces by the ′Green′ inhibitor, Ce(salicylate)3

Glen B. Deacon,*ac   Craig M. Forsyth,ac   Thomas Behrsing,ac   Kristina Konstasac  and  Maria Forsythbc  

* Corresponding authors

a School of Chemistry, Monash University, Clayton, Australia
E-mail: glen.deacon@sci.monash.edu.au
Fax: +613 99054597
Tel: +613 99054568

b School of Physics and Materials Engineering, Monash University, Clayton, Australia

c Centre for Green Chemistry, Monash University, Clayton, Australia

Abstract

The syntheses and structures of the novel Ce–Fe bimetallic complexes [{Fe(sal)2(bpy)}2Ce(NO3)(H2O)3]·EtOH and [{Fe(sal)2(bpy)}4Ce2(H2O)11][salH]2·EtOH·3H2O (salH2 = salicylic acid) suggest Fe3+–sal2− units and Ce–OC(R)O–Fe bridging contribute to the formation of corrosion inhibitive layers on steel surfaces exposed to [Ce(salH)3(H2O)].

Graphical abstract: Heterometallic CeIII–FeIII–salicylate networks: models for corrosion mitigation of steel surfaces by the ′Green′ inhibitor, Ce(salicylate)3

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Article information

DOI
https://doi.org/10.1039/B207722A
Article type
Communication
Submitted
07 Aug 2002
Accepted
07 Oct 2002
First published
25 Oct 2002

Chem. Commun., 2002, 2820-2821

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Heterometallic CeIII–FeIII–salicylate networks: models for corrosion mitigation of steel surfaces by the ′Green′ inhibitor, Ce(salicylate)3

G. B. Deacon, C. M. Forsyth, T. Behrsing, K. Konstas and M. Forsyth, Chem. Commun., 2002, 2820 DOI: 10.1039/B207722A

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