Issue 20, 2002

Peculiar magnetic behavior in ion-pair complex [1-(4′-fluorobenzyl)pyridinium][Ni(mnt)2] (mnt2− = maleonitriledithiolate)

Abstract

An ion-pair complex [FBzPy][Ni(mnt)2], where [FBzPy]+ = 1-(4′-fluorobenzyl)pyridinium and mnt2− = maleonitriledithiolate, forms a discrete stacking column and shows a peculiar magnetic transition from paramagnetic to diamagnetic around 90 K.

Graphical abstract: Peculiar magnetic behavior in ion-pair complex [1-(4′-fluorobenzyl)pyridinium][Ni(mnt)2] (mnt2− = maleonitriledithiolate)

Supplementary files

Article information

Article type
Communication
Submitted
06 Jun 2002
Accepted
28 Aug 2002
First published
17 Sep 2002

Chem. Commun., 2002, 2346-2347

Peculiar magnetic behavior in ion-pair complex [1-(4′-fluorobenzyl)pyridinium][Ni(mnt)2] (mnt2− = maleonitriledithiolate)

J. Xie, X. Ren, Y. Song, W. Zhang, W. Liu, C. He and Q. Meng, Chem. Commun., 2002, 2346 DOI: 10.1039/B205441H

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