Issue 15, 2002

A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

Abstract

A palladium(II) complex of a S–P–S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76500).

Graphical abstract: A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

Supplementary files

Article information

Article type
Communication
Submitted
11 Apr 2002
Accepted
07 Jun 2002
First published
20 Jun 2002

Chem. Commun., 2002, 1566-1567

A σ4, λ5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters

M. Doux, N. Mézailles, M. Melaimi, L. Ricard and P. Le Floch, Chem. Commun., 2002, 1566 DOI: 10.1039/B203550B

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