Issue 15, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Organically pillared microporous zirconium phosphonates

Abraham Clearfield*a  and  Zhike Wanga  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, Texas 77842-3012, USA
E-mail: Clearfield@mail.chem.tamu.edu

Abstract

There is great technological interest in the design of multifunctional microporous materials, particularly those with pores in the 10–20 Å range. The many attempts to achieve this goal through cross-linking zirconium phosphate-like layers by use of several types of diphosphonic acids will be described. A variety of functionalized pillared materials are also described with potential as sorbents and catalysts. The advances in synthetic methods now achieved promises to produce a wide variety of porous materials with controlled pore sizes and varying degrees of hydrophilic–hydrophobic character whose chemical behavior will be mediated by the incorporation of diverse functional groups as part of the pillars.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/B202371G
Article type
Perspective
Submitted
06 Mar 2002
Accepted
23 May 2002
First published
01 Jul 2002

J. Chem. Soc., Dalton Trans., 2002, 2937-2947

Permissions

Request permissions

Organically pillared microporous zirconium phosphonates

A. Clearfield and Z. Wang, J. Chem. Soc., Dalton Trans., 2002, 2937 DOI: 10.1039/B202371G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements