Issue 11, 2002
From the journal:

Chemical Communications

Novel tungsten calix[8]arene complexes†

Vernon C. Gibson,a   Carl Redshaw*b  and  Mark R. J. Elsegoodc  

* Corresponding authors

a Department of Chemistry, Imperial College, South Kensington, London, UK

b Wolfson Materials and Catalysis Centre, School of Chemical Sciences, University of East Anglia, Norwich, UK
E-mail: carl.redshaw@uea.ac.uk

c Chemistry Department, Loughborough University, Leicestershire, Loughborough, UK

Abstract

p -tert-Butylcalix[8]areneH8 reacts with WCl6 forming a number of new metallocalix[8]arenes, one of which is reduced to give the first example of a metal-metal triple bond supported by a large calixarene ligand; the degree of metallation and conformations adopted by the newly generated metallocalix[8]arene systems are determined by single crystal X-ray diffraction.

Graphical abstract: Novel tungsten calix[8]arene complexes

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Article information

DOI
https://doi.org/10.1039/B201777F
Article type
Communication
Submitted
18 Feb 2002
Accepted
17 Apr 2002
First published
02 May 2002

Chem. Commun., 2002, 1200-1201

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Novel tungsten calix[8]arene complexes

V. C. Gibson, C. Redshaw and M. R. J. Elsegood, Chem. Commun., 2002, 1200 DOI: 10.1039/B201777F

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