Issue 5, 2002
From the journal:

New Journal of Chemistry

Nitration of thiacalix[4]arene using nitrosium nitrate complexes: synthesis and characterization of tetranitro-, tetraamino-, and tetra(4-pyridylimino)tetrahydroxythiacalix[4]arene

Cédric Desroches,a   Stéphane Parola,*a   Francis Vocanson,b   Monique Perrin,b   Roger Lamartine,b   Jean-Marie Létofféa  and  Jean Bouixa  

* Corresponding authors

a Laboratoire des Multimatériaux et Interfaces (CNRS UMR 5615), Université Claude Bernard-Lyon 1, 43 Bd du 11 novembre 1918, France
E-mail: Stephane.Parola@univ-lyon1.fr

b Laboratoire de Synthèse et de Reconnaissance et Organisation Moléculaire et Biomoléculaire (CNRS UMR 5078), Université Lyon 1, France

Abstract

The chemistry of the family of thiacalixarenes remains poorly documented although the potentiality of these molecules for complexing reactions or optical applications has been demonstrated. The reaction and the mechanism of the nitration of tetrahydroxythiacalixarene are reported in this paper. The synthesis and structural characterization of 5,11,17,23-tetranitro-25,26,27,28-tetrahydroxythiacalix[4]arene, as well as its reduction to tetraaminotetrahydroxythiacalix[4]arene and the formation of tetra(4-pyridylimino)tetrahydroxythiacalix[4]arene are discussed in this article.

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Article information

DOI
https://doi.org/10.1039/B110609K
Article type
Paper
Submitted
12 Nov 2001
Accepted
15 Jan 2002
First published
23 May 2002

New J. Chem., 2002,26, 651-655

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Nitration of thiacalix[4]arene using nitrosium nitrate complexes: synthesis and characterization of tetranitro-, tetraamino-, and tetra(4-pyridylimino)tetrahydroxythiacalix[4]arene

C. Desroches, S. Parola, F. Vocanson, M. Perrin, R. Lamartine, J. Létoffé and J. Bouix, New J. Chem., 2002, 26, 651 DOI: 10.1039/B110609K

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