SCHEDULED MAINTENANCE
Formulation of a non-equilibrium model of an ionic system with a narrow acid–base boundary (representing the “electrolyte diode”) is introduced and its predictions are compared with those based on the traditional simplified model with a local electroneutrality and instantaneous local dissociation equilibria assumptions. Significant differences have been found in the spatial profiles around the acid–base boundary.
J. Lindner, D. Šnita and M. Marek, Phys. Chem. Chem. Phys., 2002, 4, 1348 DOI: 10.1039/B109525K
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