Issue 23, 2001
From the journal:

Chemical Communications

Intramolecular addition of acyl radicals to α-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol†

P. Andrew Evans,‡*a   Sushil Rainab  and  Khalid Ahsana  

* Corresponding authors

a Department of Chemistry, Indiana University, Bloomington, IN 47405, USA.
E-mail: paevans@indiana.edu
Fax: +1(812) 855-8300.

b Department of Chemistry and Biochemistry, University of Delaware, Newark, DE 19716, USA

Abstract

The level of stereocontrol obtained in the reduction of the free radical derived from the intramolecular addition of an acyl radical to an α-branched vinylogous carbonate is dependent upon the ring-size of the cyclic ether.

Graphical abstract: Intramolecular addition of acyl radicals to α-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol

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Article information

DOI
https://doi.org/10.1039/B106766B
Article type
Communication
Submitted
14 Jul 2001
Accepted
18 Sep 2001
First published
09 Nov 2001

Chem. Commun., 2001, 2504-2505

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Intramolecular addition of acyl radicals to α-substituted vinylogous carbonates: demonstrating the effect of ring size on acyclic stereocontrol

P. A. Evans<affref idrefs="affa" xmlns="http://www.rsc.org/schema/rscart38" />, S. Raina and K. Ahsan, Chem. Commun., 2001, 2504 DOI: 10.1039/B106766B

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