Issue 1, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Isolation and characterization of the first bis(2-pyridyl)carbyltitanium(iv) complex derived from the C–O bond cleavage of the alkoxide ligand in Cp*TiMe2(OCMePy2). X-Ray crystal structure of [Cp*Ti(μ-O)(CMePy2)]2 (Cp* = C5Me5)†

Rosa Fandos,*a   Carolina Hernández,a   Antonio Otero,*b   Ana Rodríguez,c   Maria José Ruiza  and  Pilar Terrerosd  

* Corresponding authors

a Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Facultad de Ciencias del Medio Ambiente. Avd. Carlos III, s/n 45071 Toledo, Spain

b Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, Facultad de Químicas, Campus de Ciudad Real, Avd. Camilo José Cela, 10, 13071 Ciudad Real, Spain

c Departamento de Química Inorgánica, Orgánica y Bioquímica, Universidad de Castilla-La Mancha, ETS Ingenieros Industriales, Campus de Ciudad Real, Avd. Camilo José Cela, 3, 13071 Ciudad Real, Spain

d Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, 28049 Madrid, Spain

Abstract

The reaction of Cp*TiMe2(OCMePy2) with one equivalent of xylylisocyanide (xylyl = 2,6-dimethylphenyl) affords the first bis(2-pyridyl)carbyl titanium(IV) as final complex in which the ligand acts as chelate and it is directly bonded to the titanium atom through both nitrogen atoms.

Graphical abstract: Isolation and characterization of the first bis(2-pyridyl)carbyltitanium(iv) complex derived from the C–O bond cleavage of the alkoxide ligand in Cp*TiMe2(OCMePy2). X-Ray crystal structure of [Cp*Ti(μ-O)(CMePy2)]2 (Cp* = C5Me5)

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Article information

DOI
https://doi.org/10.1039/B106481A
Article type
Communication
Submitted
19 Jul 2001
Accepted
23 Nov 2001
First published
05 Dec 2001

J. Chem. Soc., Dalton Trans., 2002, 11-13

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Isolation and characterization of the first bis(2-pyridyl)carbyltitanium(IV) complex derived from the C–O bond cleavage of the alkoxide ligand in Cp*TiMe2(OCMePy2). X-Ray crystal structure of [Cp*Ti(μ-O)(CMePy2)]2 (Cp* = C5Me5)

R. Fandos, C. Hernández, A. Otero, A. Rodríguez, M. J. Ruiz and P. Terreros, J. Chem. Soc., Dalton Trans., 2002, 11 DOI: 10.1039/B106481A

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