Issue 18, 2001
From the journal:

Chemical Communications

The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal–organic derivatives of polyoxometalates: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo 5O15){O3P(CH2)4 PO3}]·H2O and [{Cu2(tpypyz)(H2O)2}(Mo5 O15)(O3PCH2CH2PO3 )]·5.5H2O [bpy = 2,2′-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]

Robert C. Finn,a   Eric Burkholdera  and  Jon Zubieta*a  

* Corresponding authors

a Department of Chemistry, Syracuse University, Syracuse, NY, USA.
E-mail: jazubiet@syr.edu

Abstract

The hydrothermal reaction of CuSO4·5H2O, Na2MoO4·2H2O and 2,2′-bipyridine with the bridging diphosphonate ligand H2O3P(CH2)4PO3H 2 yields the one-dimensional chain [{Cu(bpy)2}{Cu(bpy)(H2O)2 }(Mo5O15){O3P(CH2) 4PO3}]·H2O; the introduction of a second bridging component in the reaction of Cu(MeCO2)2·H2O, MoO3, H2O3PCH2CH2PO3H 2 and tetra(2-pyridyl)pyrazine yields the network solid [{Cu2(tpypyz)(H2O)2}(Mo5 O15)(O3PCH2CH2PO3 )]·5.5H2O.

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Article information

DOI
https://doi.org/10.1039/B104860K
Article type
Feature Article
Submitted
04 Jun 2001
Accepted
15 Aug 2001
First published
03 Sep 2001

Chem. Commun., 2001, 1852-1853

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The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal–organic derivatives of polyoxometalates: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo 5O15){O3P(CH2)4 PO3}]·H2O and [{Cu2(tpypyz)(H2O)2}(Mo5 O15)(O3PCH2CH2PO3 )]·5.5H2O [bpy = 2,2′-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine]

R. C. Finn, E. Burkholder and J. Zubieta, Chem. Commun., 2001, 1852 DOI: 10.1039/B104860K

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