Issue 17, 2001
From the journal:

Chemical Communications

A new palladium-catalysed synthesis of 1,1-dialkylbuta-1,3-dienes via organoboron intermediatesDedicated to Professor Iacopo Degani on the occasion of his 70th birthday.

Paolo Balma Tivola,a   Annamaria Deagostino,a   Cristina Prandi*b  and  Paolo Venturello*a  

* Corresponding authors

a Dipartimento di Chimica Generale ed Organica Applicata dell’Università, Corso M. D’Azeglio, 48, Torino, Italy.
E-mail: venturello@ch.unito.it;
Fax: 0039 0116707642;
Tel: 0039 0116707646

b Dipartimento di Scienze e Tecnologie Avanzate dell’Università, Corso Borsalino, 54, Alessandria, Italy

Abstract

Iodobenzene and tetrakis(triphenylphosphine)palladium(0) [(C6H5)3P]4Pd catalyse a new synthesis of 1,1-dialkylbuta-1,3-dienes, starting from 1,1-diethoxybut-2-ene and trialkylboranes, in the presence of Schlosser’s superbase LIC–KOR.

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Article information

DOI
https://doi.org/10.1039/B104449B
Article type
Communication
Submitted
21 May 2001
Accepted
26 Jun 2001
First published
31 Jul 2001

Chem. Commun., 2001, 1536-1537

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A new palladium-catalysed synthesis of 1,1-dialkylbuta-1,3-dienes via organoboron intermediates

P. B. Tivola, A. Deagostino, C. Prandi and P. Venturello, Chem. Commun., 2001, 1536 DOI: 10.1039/B104449B

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