Issue 15, 2001
From the journal:

Chemical Communications

The effect of N-methylation on the chemical reactivity of binuclear Ni amine-thiophenolate complexesElectronic supplementary information (ESI) available: Characterization data for all new compounds. ORTEP plots for complexes 5 and 6. See http://www.rsc.org/suppdata/cc/b1/b103050g/

Berthold Kersting*a  and  Gunther Steinfelda  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie, Universität Freiburg, Albertstr. 21, Freiburg, Germany.
E-mail: kerstber@sun2.ruf.uni-freiburg.de

Abstract

Macrocyclic amine thiophenolate ligands are shown to form face-sharing bioctahedral nickel complexes with a central N3Ni(μ-SR)2(μ-Cl)NiN3 core structure. The bridging halide ion can be readily replaced when all six nitrogen atoms are tertiary amine donors.

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Article information

DOI
https://doi.org/10.1039/B103050G
Article type
Communication
Submitted
04 Apr 2001
Accepted
20 Jun 2001
First published
06 Jul 2001

Chem. Commun., 2001, 1376-1377

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The effect of N-methylation on the chemical reactivity of binuclear Ni amine-thiophenolate complexes

B. Kersting and G. Steinfeld, Chem. Commun., 2001, 1376 DOI: 10.1039/B103050G

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