Issue 9, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Nickel(II) in an almost regular tetrahedral thiolate environment: a first generation synthetic analogue of the active site of nickel CO-dehydrogenase

Matt C. Smith,a   Steven Longhurst,a   J. Elaine Barclay,a   Stephen P. Cramer,b   Sian C. Davies,a   David L. Hughes,a   Wei-Wei Gub  and  David J. Evans*a  

* Corresponding authors

a Department of Biological Chemistry, John Innes Centre, Norwich Research Park, Colney, Norwich, UK
E-mail: dave.evans@bbsrc.ac.uk

b Department of Applied Science, University of California Davis, USA

Abstract

Reaction of the iron(II)–carbonyl chelate ligand [Fe(NS3)(CO)]− [NS3 = N(CH2CH2S)33−] with the dmso solvate of nickel(II) chloride gives the structurally characterised trinuclear linear complex [Ni{Fe(NS3)(CO)-S,S ′}2], which has an almost regular tetrahedral arrangement of sulfur about nickel and structural features similar to those proposed for the active site of nickel CO-dehydrogenase.

Graphical abstract: Nickel(II) in an almost regular tetrahedral thiolate environment: a first generation synthetic analogue of the active site of nickel CO-dehydrogenase

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Article information

DOI
https://doi.org/10.1039/B102607K
Article type
Communication
Submitted
20 Mar 2001
Accepted
21 Mar 2001
First published
30 Mar 2001

J. Chem. Soc., Dalton Trans., 2001, 1387-1388

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Nickel(II) in an almost regular tetrahedral thiolate environment: a first generation synthetic analogue of the active site of nickel CO-dehydrogenase

M. C. Smith, S. Longhurst, J. E. Barclay, S. P. Cramer, S. C. Davies, D. L. Hughes, W. Gu and D. J. Evans, J. Chem. Soc., Dalton Trans., 2001, 1387 DOI: 10.1039/B102607K

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