Issue 12, 2001
From the journal:

Chemical Communications

Imine chloroboration: reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidineElectronic supplementary information (ESI) available: Experimental details and characterisation data for 1. See http://www.rsc.org/suppdata/cc/b1/b101580j/

Francis S. Mair,*a   Robert Manning,a   Robin G. Pritcharda  and  John E. Warrena  

* Corresponding authors

a Department of Chemistry, UMIST, PO Box 88, Manchester, UK
E-mail: frank.mair@umist.ac.uk

Abstract

Reaction of N,N′-bis(2,6-diisopropylphenyl)-1,4-diazadiene with BCl3 in hexane gave the crystalline product of double chloroboration, N,N′-bis(2,6-diisopropylphenyl)2,4,5-trichloro-1,3,2-diazab orolidine, which was characterised by single crystal X-ray diffraction, microanalysis and multinuclear NMR spectroscopy.

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Article information

DOI
https://doi.org/10.1039/B101580J
Article type
Communication
Submitted
19 Feb 2001
Accepted
03 May 2001
First published
31 May 2001

Chem. Commun., 2001, 1136-1137

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Imine chloroboration: reaction of boron trichloride with a bulky diazadiene gives not a diazaborolium salt, but a 2,4,5 trichloro-1,3,2-diazaborolidine

F. S. Mair, R. Manning, R. G. Pritchard and J. E. Warren, Chem. Commun., 2001, 1136 DOI: 10.1039/B101580J

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