The preparation, X-ray crystal structures and electrochemical properties of bis(2-cyano-1,2-ethanedithiolate)nickelate [Ni(edt-CN)2]2−/−· are described for both oxidation states together with the singlet–triplet behaviour of the PPh4+ salt of the paramagnetic [Ni(edt–CN)2]−· complex.
[Ni(edt-CN)2]−·, a novel paramagnetic nickel dithiolene complex analog of Ni(mnt)2−· with two cyano groups only
M. Fourmigué and J. N. Bertran, Chem. Commun., 2000, 2111 DOI: 10.1039/B006440H
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