Issue 23, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Multicomponent Zn-tetraphenylporphyrins: syntheses, characterization and their self assembly in the solid state

Atindra D. Shukla,a   Paresh C. Dave,a   Eringathodi Suresh,a   Amitava Das*a  and  Parthasarathi Dastidar*a  

* Corresponding authors

a Silicates & Catalysis Division, Central Salt & Marine Chemicals Research Institute, G. B. Marg, Bhavnagar, India

Abstract

Two multicomponent Zn-tetraphenylporphyrin (ZnTPP) based building blocks have been synthesized for designing microporous crystalline solids. Reactions of ZnTPP with 4,4′-bipyridine (4,4′-bpy) in two different molar ratios gave two coordination complexes namely [(ZnTPP)3{μ-4,4′-bpy}2] I and [(ZnTPP)2{μ-4,4′-bpy}] II. Complexes I and II were characterized by spectroscopic and analytical methods. Inclusion complexes of I with toluene, II with toluene, and also with nitrobenzene have been prepared and are characterized by 1H NMR and single crystal X-ray diffraction techniques. Supramolecular structural systematics of TPP-based materials are conserved in these crystals.

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Article information

DOI
https://doi.org/10.1039/B004211K
Article type
Paper
Submitted
26 May 2000
Accepted
13 Oct 2000
First published
16 Nov 2000

J. Chem. Soc., Dalton Trans., 2000, 4459-4463

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Multicomponent Zn-tetraphenylporphyrins: syntheses, characterization and their self assembly in the solid state

A. D. Shukla, P. C. Dave, E. Suresh, A. Das and P. Dastidar, J. Chem. Soc., Dalton Trans., 2000, 4459 DOI: 10.1039/B004211K

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