Issue 18, 2000

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorus oxoanions

Abstract

The reaction of PCl3 with 3 equivalents of 2-methoxyaniline in THF/NEt3, followed by metallation with BunLi (2 equivalents) yields a complex [Li2P(H)(NR)3]2 1 (R = 2-methoxyphenyl), whose tris imido phosphonate anion is the imido analogue of the phosphite anion, [HPO3]2−.

Supplementary files

Article information

Article type
Communication
Submitted
25 May 2000
Accepted
04 Aug 2000
First published
31 Aug 2000

Chem. Commun., 2000, 1769-1770

Synthesis and structure of a tris imido phosphonate anion; the missing link in imido analogues of phosphorus oxoanions

L. T. Burke, E. Hevia-Freire, R. Holland, J. C. Jeffery, A. P. Leedham, C. A. Russell, A. Steiner and A. Zagorski, Chem. Commun., 2000, 1769 DOI: 10.1039/B004192K

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