Issue 17, 2000
From the journal:

Chemical Communications

Michael addition of N-bonded enolato ligands to acrylonitrile in iron and ruthenium complexesElectronic supplementary information (ESI) available: physical and spectroscopic data for 1a and 1b. See http://www.rsc.org/suppdata/cc/b0/b004099l/

Masafumi Hirano,a   Sayori Kiyota,a   Masataka Imotoa  and  Sanshiro Komiya*a  

* Corresponding authors

a Department of Applied Chemistry, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei, Tokyo, Japan.
E-mail: komiya@cc.tuat.ac.jp

Abstract

Treatment of the N-bonded enolatoiron(II) complex [M(H)(NCCHCO2R)(L)2] [1a, M = Fe, R = Me, L = depe {1,2-bis(diethylphosphino)ethane}; 1b, M = Fe, R = Et, L = depe; 2, M = Ru, L = dppe] with acrylonitrile results in mono-Michael addition to give [M(H){NCC(C2H4CN)CO2R}(L)2 ], which is found to be an active intermediate for the catalytic double-Michael reaction of cyanoacetate with acrylonitrile.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B004099L
Article type
Communication
Submitted
22 May 2000
Accepted
26 Jul 2000
First published
23 Aug 2000

Chem. Commun., 2000, 1679-1680

Permissions

Request permissions

Michael addition of N-bonded enolato ligands to acrylonitrile in iron and ruthenium complexes

M. Hirano, S. Kiyota, M. Imoto and S. Komiya, Chem. Commun., 2000, 1679 DOI: 10.1039/B004099L

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements