Issue 9, 2000

Abstract

The electrical resistivity and Seebeck coefficient of (R0.9Ca0.1)CoO3 (R = Gd, Sm, Nd, Pr) rapidly decrease with increasing ionic radius of the rare-earth element, and the Seebeck coefficients (p-type) are fairly high at low temperatures and attain low and constant values at high temperatures; (Pr0.9Ca0.1)CoO3 shows the highest figure-of-merit, 1.3 × 10−4 K−1 at 85 °C, although this rapidly decreases with temperature above 300 °C due to the decreasing Seebeck coefficient and increasing electronic thermal conductivity.

Article information

Article type
Communication
Submitted
17 May 2000
Accepted
28 Jun 2000
First published
07 Aug 2000

J. Mater. Chem., 2000,10, 2007-2009

Ca-doped RCoO3 (R = Gd, Sm, Nd, Pr) as thermoelectric materials

J. Moon, W. Seo, H. Okabe, T. Okawa and K. Koumoto, J. Mater. Chem., 2000, 10, 2007 DOI: 10.1039/B003964K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements