Volatile, thermally robust 1,1-dimethylhydrazidogallane, [H2GaN(H)NMe2]21 has been synthesized from the reaction of H3Ga(NMe3) with H2NNMe2, whereas reaction of compound 1 with an excess of H2NNMe2 at elevated temperature afforded a gallium hydrazide derivative, Ga4[N(H)NMe2]8(NNMe2)2 2, which possessed a novel structure of two Ga2N2 rings bridged by NNMe2 groups.
1,1-Dimethylhydrazidogallane and a gallium hydrazide
with two Ga2N2 rings bridged by two NNMe2
B. Luo and W. L. Gladfelter, Chem. Commun., 2000, 825 DOI: 10.1039/B001010N
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