Issue 8, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host

Michael G. B. Drew,a   Oliver W. Howarth,b   Noreen Martin,d   Grace G. Morgand  and  Jane Nelsond  

a Chemistry Department, The University, Reading, UK

b Department of Chemistry, University of Warwick, Coventry, UK

c School of Chemistry, Queens University, Belfast, UK

d Open University, Milton Keynes, UK

Abstract

The crystal structure of a thallium(III) iminophenolate cryptate is reported. Tl(III) is strongly held within the host, as judged by NMR indicators of strength of binding, by both imino-N, (via203,205Tl,15N coupling of over 1000 Hz in the MAS-CP spectrum) and phenolate-O donors (via the weakness of competitive H-bonding to the phenolate O− groups, seen in the solution 1H spectrum).

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Article information

DOI
https://doi.org/10.1039/B000736F
Article type
Paper
Submitted
27 Jan 2000
Accepted
02 Mar 2000
First published
31 Mar 2000

J. Chem. Soc., Dalton Trans., 2000, 1275-1278

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Encapsulated Tl(III) strongly retained within an iminophenolate cryptand host

M. G. B. Drew, O. W. Howarth, N. Martin, G. G. Morgan and J. Nelson, J. Chem. Soc., Dalton Trans., 2000, 1275 DOI: 10.1039/B000736F

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