Issue 6, 2000
From the journal:

Chemical Communications

The N,N′-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(iii) bis(benzamidinate) alkyl catalystElectronic supplementary information (ESI) available. Synthetic and spectroscopic details and ethene oligomerisation experiments. See http://www.rsc.org/suppdata/cc/b0/b000397mNetherlands Institute for Catalysis Research (NIOK) publication no. RUG 99-4-05.

Edward A. C. Brussee,a   Auke Meetsma,a   Bart Hessen*a  and  Jan H. Teubena  

* Corresponding authors

a Centre for Catalytic Olefin Polymerisation, Stratingh Institute of Chemistry and Chemical Engineering, University of Groningen, Nijenborgh 4, AG Groningen, The Netherlands.
E-mail: hessen@chem.rug.nl

Abstract

The pentafluorobenzamidinate ligand [C6F5C(NSiMe3)2]− is reported, together with its bis(benzamidinate) vanadium(III) methyl derivative; the latter is considerably more active in catalytic ethene oligomerisation than its non-fluorinated analogue.

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Article information

DOI
https://doi.org/10.1039/B000397M
Article type
Communication
Submitted
20 Dec 1999
Accepted
18 Feb 2000
First published
08 Mar 2000

Chem. Commun., 2000, 497-498

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The N,N′-bis(trimethylsilyl)pentafluorobenzamidinate ligand: enhanced ethene oligomerisation with a neutral V(III) bis(benzamidinate) alkyl catalyst

E. A. C. Brussee, A. Meetsma, B. Hessen and J. H. Teuben, Chem. Commun., 2000, 497 DOI: 10.1039/B000397M

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